Product ID:SODIUM FLUORIDE
MSDS Date:10/15/1987
FSC:6810
NIIN:00-680-1079
MSDS Number: BLLVR

J.T.BAKER CHEMICAL CO.

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865-2219
US

Emergency Phone: 201-859-2151/CHEMTREC 800-424-9300

Info Phone: 201-859-2151

Cage: DO870

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

SODIUM FLUORIDE (SARA III)

CAS: 7681-49-4

RTECS: WB0350000

Fraction By Weight: 99- 100%

OSHA PEL 2.5 PPM F

ACGIH TLV: 2.5 MG F/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 64 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYES/SKIN:MAY CAUSE SEVERE
IRRITATION/BURNS.INHALATION:DUST MAY CAUSE SEVERE IRRITATION OF
RESPIRATORY SYSTEM.INGESTION:MAY CAUSE
HEADACHE,NAUSEA,VOMITING,GASTROINTESTINAL IRRITATION,CONVULSIONS ,&
BURNS TO MOUTH,THROAT & STOMACH.CHRONIC-CALCIUM DEPOSITS IN
LIGAMENTS,INCREASED BONE DENSITY & MOTTLED TOOTH ENAMEL.
Effects of Overexposure:SEVERE IRRITATION AND BURNS OF EYE AND SKIN.
INHALATION OF DUST MAY CAUSE SEVERE IRRITATION OF RESPIRATORY
TRACT. INGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING,
GASTROINTESTINAL IRRITATION, CONVULSIO NS, & BURNS TO MOUTH, THROAT
& STOMACH.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED

First Aid:CALL A PHYSICIAN IN ALL CASES.INHALATION:REMOVE TO FRESH
AIR.GIVE CPR/OXYGEN IF NEEDED.EYES:IMMEDIATELY FLUSH WITH WATER FOR
15 MINUTES HOLDING EYELIDS OPEN.SKIN:REMOVE CONTAMINATED
CLOTHING.FLUSH SKI N WITH WATER.INGESTION:IF CONSCIOUS,IMMEDIATELY
INDUCE VOMITING.

Flash Point:NONE
Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR PROPER PROTECTIVE
EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HEAT MAY
EXPLODE. TOXIC HYDROGEN FLUORIDE CAN BE PRODUCED.

Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE CLOTHING. WITH CLEAN SHOVEL, CAREFULLY PLACE
MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA.
FLUSH SPILL AREA WITH WATER.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORAGE-STORE IN SECURE POISON AREA.DO
NOT STORE IN GLASS.KEEP AWAY FROM ACIDS.
Other Precautions:SODIUM FLUORIDE REACTS WITH ACIDS TO FORM HF, WHICH
IS HIGHLY CORROSIVE & POISONOUS. DO NOT TAKE INTERNALLY. AVOID
BREATHING OF DUSTS. AVOID CONTACT WITH EYES AND SKIN. USE WITH
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST.IF AIRBORNE CONCENTRATION EXCEEDS TLV, A DUST/MIST
RESPIRATOR IS RECOMMENDED. IF CONCENTRATION EXCEEDS CAPACITY OF
RESPIRATOR, A SELF-CONTAINE D BREATHING APPARATUS IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:NEOPRENE, NITRILE OR NATURAL RUBBER
Eye Protection:DUST-RESISTANT SAFETY GOGGLES
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, UNIFORM
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING.
Supplemental Safety and Health

HCC:T4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=1703.9C, 3099.F
Melt/Freeze Pt:=992.8C, ######F
Spec Gravity:2.78
Solubility in Water:APPRECIABLE (>10%)
Appearance and Odor:WHITE ODORLESS CRYSTALS OR POWDER
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, GLASS
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:HYDROGEN FLUORIDE

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.